Product ID:1601 GLOSSY BLACK DECORATOR PAINTS
MSDS Date:12/01/1996
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKRJV

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC

31500 SOLON ROAD
SOLON, OH 44139
US

Emergency Phone: 216-566-2917

Info Phone: 800-247-3270; 800-832-2541

Cage: TO019

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC

SOLON, OH 44139 US

Telephone: 800-247-3270; 216-566-2917

Cage: TO019

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

BUTANE

CAS: 106-97-8

RTECS: EJ4200000

ACGIH TLV: 1900 MG/M3;800 PPM

ETHYLBENZENE

CAS: 100-41-4

RTECS: DA0700000

OSHA PEL 435 MG/M3;100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETONE

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ETHYL KETONE

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 590 MG/M3;200 PPM

ACGIH TLV: 590 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1-METHOXY-2-PROPANOL ACETATE

CAS: 108-65-6

RTECS: AI8925000

1-BUTANOL

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 300 MG/M3;100 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. MAY CAUS E NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
CHRONIC: PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE
ADVERSE AFFECTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR, &
REPRODUCTIVE SYSTEMS. METHYL ETHYL KETONE MAY INCREASE THE NERVOUS
SYSTEM EFFECTS OF OTHER SOLVENTS. REPORTS HAVE ASSOCIATED REPEATED
& PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN NERVOUS
SYSTEM DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENTS IN THESE PRODUCTS IS AN
IARC, NTP OR OSHA LISTED CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS AND
SPRAY MISTS. TENDERNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EX POSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:IF INHALED:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE- USE. IF IN EYES: FLUSH EYES WITH LARGE AMOUNTS
OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE
VOMITING. GIVE CONSCIO US PATIENT SEVERAL GALSSES OF WATER. SEEK
MEICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<-17.6C, 0.F
Lower Limits:1.0
Upper Limits:13.1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED FOG NOZZLES ARE PREFERABLE WATER
MAY BE USED TO COOL CLOSED CONT AINERS TO PREVENT PRESSURE BUILD-UP
AND ALSO POSSIBLE SUTOIGNITION OR LASION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO THE
BUILDUP OF PRESSURE WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM
HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME. APPLICATION TO HOT
SURFACES REQUIRES SPECIAL PRE CAUTIONS. DURING EMERGENCY CONDITIONS
OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN
FLAME. VAPORS WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY.
DURING USE & UNTIL ALL VAPORS ARE GONE. KEEP AREA VENTILATED-DO NOT
SMOKE-EXTINGUISH ALL FLAMES, PIL OT LIGHTS, & HEATERS. TURN OFF
STOVES, ELECTRICAL TOOLS & APPLIANCES, & ANY OTHER IGNITION
SOURCES.
Other Precautions:CONSULT NFPA CODE. USE APPROVED BONDING/GROUNDING
PROCEDURES. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE,
OR EXPOSE TO TEMPERATURE ABOVE 120F. HEAT FROM SUN, RADIATORS,
STOVES, HOT WATER AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO
BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHI LDREN.

Respiratory Protection:WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATORY APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS
IN INGREDIENTS SECTION. WHEN SANDING OR ABRADING THE DRIED FILM,
WEAR A DUST/MIST R ESPIRATOR APPROVED BY NIOSH/MSHA FOR DUST WHICH
MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT, OR THE
ABRASIVE.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERIALS IN INGREDIENTS IS MAINTAINED BELOW EXPOSURE
LIMITS.
Protective Gloves:NONE FOR REPEATED CONTACT WEAR CHEMICAL RESISTANT
GLOVES.
Eye Protection:SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Work Hygienic Practices:USE ONLY WITH ADEQUATE VENTILATION. AVOID
BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES.
WASH HANDS AFTER USING.
Supplemental Safety and Health
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS CAN BE HARMFUL OR FATAL.

HCC:V3
Boiling Pt:B.P. Text:0 TO 302
Vapor Density:>AIR
Spec Gravity:11
VOC Grams/Liter:3.37
Evaporation Rate & Reference:>ETHER

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF METALS.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER THE RCRA 40CFR261. WASTE MUST BE TREATED FOR
IGNITABILITY TO DETERMINE THE APPLICABILITY OF EPA HAZARDOUS WASTE
NUMBERS. WASTE FROM PRODUCTS C ONTAINING METHYL ETHYL KETONE OR
COPPER MAY REQUIRE TESTING FOR EXTRACTIBILITY. DO NOT INCINERATE. D
ISPOSE OF I/A/W FEDERAL, STATE & LOCAL LAWS.

Toxicological Information:RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250
MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT
ATTAINABLE IN THE WORKPLACE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THESE PRODUCTS ARE LISTED, OR ARE EXPEMT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THESE
PRODUCTS CONTAINS A CHEMICAL/S KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.